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The practical application of lithium (Li) metal anode (LMA) is still hindered by non‐uniformity of solid electrolyte interphase (SEI), formation of “dead” Li, and continuous consumption of electrolyte although LMA has an ultrahigh theoretical specific capacity and a very low electrochemical redox potential. Herein, a facile protection strategy is reported for LMA using a double layer (DL) coating that consists of a polyethylene oxide (PEO)‐based bottom layer that is highly stable with LMA and promotes uniform ion flux, and a cross‐linked polymer‐based top layer that prevents solvation of PEO layer in electrolytes. Li deposited on DL‐coated Li (DL@Li) exhibits a smoother surface and much larger size than that deposited on bare Li. The LiF/Li₂O enriched SEI layer generated by the salt decomposition on top of DL@Li further suppresses the side reactions between Li and electrolyte. Driven by the abovementioned advantageous features, the DL@Li||LiNi_0.6Mn_0.2Co_0.2O₂cells demonstrate capacity retention of 92.4% after 220 cycles at a current density of 2.1 mA cm^–2(C/2 rate) and stability at a high charging current density of 6.9 mA cm^–2(1.5 C rate). These results indicate that the DL protection is promising to overcome the rate limitation of LMAs and high energy‐density Li metal batteries.